1 cup very hot water (8 fluid ounces)
2 ounces semisweet baking chocolate, finely chopped
1 tablespoon instant coffee powder
400 grams (14.1 ounces) granulated sugar
100 grams (3.5 ounces) Dutch process cocoa powder
220 grams (7.75 ounces) all-purpose flour
1/2 tablespoon baking soda
1 1/4 teaspoons baking powder
3/4 teaspoon salt
8 ounces buttermilk
4 1/2 fluid ounces vegetable oil
2 large eggs
2 teaspoons pure vanilla extract
4 sticks (2 cups) unsalted butter, softened
28 ounces sifted confectioners' sugar
3 tablespoons milk, plus teaspoons for thinning as needed
2 teaspoons vanilla extract
Pinch of salt
3/4 cup creamy natural-style peanut butter
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